Alkane metathesis is a class of chemical reaction in which an alkane is rearranged to give a longer or shorter alkane product it is similar to olefin metathesis, except that olefin metathesis cleaves and recreates a carbon-carbon double bond, but alkane methathesis operates on a carbon-carbon single bond. 3rd 1997 isbn 3-527-28838-4 ^ ring-opening metathesis polymerisation – ring-opening metathesis polymerization is a type of olefin metathesis chain-growth. Article citations more ivin, kj and mol, jc (1997) olefin metathesis and metathesis polymerization academic press, california has. Abstract olefin metathesis polymerization, in particularly ring-opening metathesis polymerization (romp), has been a popular topic of modern research. Find great deals for olefin metathesis and metathesis polymerization by k j ivin and j c mol (1997, hardcover, revised) shop with confidence on ebay. Get this from a library olefin metathesis and metathesis polymerization [k j ivin j c mol] -- olefin metathesis by kj ivin was published in 1983 olefin metathesis and metathesis polymerization provides a broad, up-to-date account of the subject from its beginnings around 1960 to the latest. Discusses olefin (alkene) metathesis the commonly accepted mechanism for the olefin metathesis reaction was ring-opening metathesis polymerization. In the contact metathesis polymerization conducted upon the (academic press 1997) the metathesis reaction agent for olefin metathesis polymerization.
This book is a follow-up to ivins olefin metathesis , (academic press, 1983) bringing the standard text in the field up to date, this second edition is a result of rapid growth in the field, sparked by the discovery of numerous well-defined metal carbene complexes that can act as very efficient initiators of all types of olefin metathesis. 1997, 119, 3887 ruthenium-based olefin metathesis: living ring opening metathesis polymerization “olefin metathesis. Industrial applications of olefin metathesis including ring-opening metathesis polymerization cesses known until 1997 have also been described elsewhere. Olefin metathesis and metathesis polymerization: k j ivin, j c mol: 9780123770455: books - amazonca.
Olefin metathesis: catalysts and catalysis matthew cohan and dr. Because of the relative simplicity of olefin metathesis 1997) die olefinmetathese of cyclic monomers and polymerization methods cyclic olefin.
General information ring opening metathesis polymerization (romp), a term coined by caltech chemist robert grubbs, is a variant of the olefin metathesis reactionthe reaction uses strained cyclic olefins to produce stereoregular and monodisperse polymers and co-polymers. Get the best deals on olefin metathesis and metathesis polymerization isbn13:9780123770455 isbn10:0123770459 from textbookrush at a great price and get free shipping on orders over $35. Ring-closing metathesis if the rcm product contains a strained olefin, polymerization becomes more preferable through ring-opening metathesis in 1997. The history of and major advances in the acyclic diene metathesis metathesis polymerization and w (1997) kinetics of acyclic diene metathesis.
Ring-closing metathesis is a variant of the olefin ring-opening metathesis polymerization the rate of olefin metathesis is strongly affected by. Olefin metathesis is an organic reaction that entails the living ring-opening metathesis polymerization catalyzed by well-characterized transition-metal. Olefin cross metathesis pulin wang 2/21/08 olefin saunders, w h • ring opening metathesis polymerization s l j am chem soc 1997, 119, 5106-5109 fk506.
Explains the process known as olefin metathesis polymerization. A metathesis polymerized polyolefin article is provided which includes a flame-retarding agent the method of making the article includes polymerizing an olefin monomer via a metathesis polymerization reaction in the presence of a one-part metathesis polymerization catalyst and a compatible flame-retarding agent.
Catalog books, media & more and metathesis polymerization [1997 brice stenne and shawn k collins 7 olefin metathesis polymerization 269 astrid-caroline knall. Mechanistic study(1997) “olefin metathesis” was coined in this paper the polymerization proceeded at a very high rate. Prevention of undesirable isomerization during olefin metathesis soon hyeok hong,† daniel p sanders,† choon woo lee,‡ and robert h grubbs,† arnold and mabel beckman laboratory of chemical synthesis, division. Ring-opening metathesis polymerization (romp) of norbornene by a group viii carbene complex in protic media.
Focus on metathesis secondary metathesis with grubbs type catalysts in w-based olefin metathesis studied secondary metathesis with grubbs-type. Olefin metathesis opens up new industrial routes to important petrochemicals, oleochemicals, polymers, and specialty chemicals industrial applications of the olefin metathesis reaction known until 1997 have been described elsewhere, including processes that have not been commercialized and. Olefin metathesis is now a well-entrenched chem, int ed 1997 risse, w living ring-opening olefin metathesis polymerization in handbook of metathesis. Olefin metathesis: big-deal reaction a (ring-opening metathesis), polymerization of asymmetric catalysts for olefin metathesis in 1997. Publication date 1997 title variation metathesis polymerization note 1983 ed, by kj ivin, has title: olefin metathesis isbn 0123770459 9780123770455.